Hi zeddy,
I'm not familiar with Live on PCs or Windows PCs in general. However, I believe that the interface for Live on Mac and PC is identical and the key commands should match too. Only issue I believe is that Mac's have different names and symbols for some modifier keys (e.g. Command and Option) - mostly on the PC Command key = Control and Option = Alt.
I'm not sure which version of Windows you are running - but do check before purchase that our download Tutorial Player (N.E.D) works fine on your system:
http://www.macprovideo.com/about/ned&os=win&ver=win
as NED for Windows does not currently support 64bit Windows. In which case I'd recommend the subscription option which gives you online access to the library of tutorials offered on a monthly basis.
The HD file will be in the region of 900MB.
Do download NED and try out some of the free demo tutorials to get a feel for how the system works.
Best
Rounik